Varberg  Lab

 

Molecules.

Light.

Spectroscopy.

 
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NEWS
 

 Picture of Helsinki, Finland

just published! 
april 2018

Our second paper on gold sulfide (AuS) has just been published, by the journal Molecular Physics, as part of a special issue from the HRMS Conference I presented at last August in Helsinki, Finland. (Since it's a British journal, the molecule had to be spelled gold sulphide!) We report on a high-resolution analysis of the a⁴Σ⁻₃⸝₂–X²Π₃⸝₂ system in the near-infrared. It is the first spin-forbidden transition we have ever studied. The transition intensity is provided by the strong spin–orbit coupling of the heavy gold atom. My co-authors are Austin Parsons (now earning his Ph.D. in Bob Continetti's research group at UC–San Diego) and Sam Gleason, who is a Macalester senior.

 
 Picture of University of Chicago

Andersen lecture
November 2017

On November 3, 2017, I had the privilege of presenting the Janet Andersen Award Lecture for the Midstates Consortium for Math and Science. What made the event extra special for me was the opportunity to deliver the talk at the University of Chicago, one of the world's great research universities and the former academic home of Prof. Robert Mulliken. He was one of the great molecular spectroscopists, co-developer of molecular orbital theory, and a Nobel laureate in chemistry. 

 Picture of Florence, Italy

Sabbatical
Fall 2013

I spent my sabbatical of Fall 2013 in Switzerland and Italy. I am particularly grateful for the warm welcome from my two local hosts, Prof. Frédéric Merkt of ETH Zürich and Prof. Paolo de Natale of the University of Florence, and their research groups. Switzerland and Italy are wonderful places to spend a sabbatical!

 
 Picture of Professor in front of research poster

Tom Varberg

DeWitt Wallace Professor of Chemistry

I have been teaching Physical and General Chemistry at Macalester College since 1993. My research is focused on the electronic spectroscopy of metal-containing free radicals in the gas phase, particularly their fine and hyperfine structures. We utilize pulsed and continuous-wave lasers (both dye and Ti:sapphire), often working at very high resolution. We seek to unravel and assign the complicated spectra of these open-shell free radicals, thus deciphering their Hamiltonians and illuminating their electronic structure.  Some of these molecules are of astronomical interest, as this image of the Orion Molecular Cloud Complex suggests.

I received my B.A. degree in chemistry in 1985 from Hamline University and my Ph.D. degree in physical chemistry from MIT in 1990. I was a postdoctoral scholar at the National Institute of Standards and Technology from 1990–92 and a NATO Postdoctoral Fellow at the University of Oxford from 1992–93. In this training, I explored the spectroscopy of free radicals using a variety of experimental techniques and wavelengths (microwave, far-infrared and visible).

I have had four sabbatical leaves from Macalester College, taken in (1) Boulder, Colorado, (2) Vancouver, British Columbia, (3) Sydney, Australia, and (4) Zürich, Switzerland & Florence, Italy, as well as two research summers spent at the University of Oxford, England.

I take as my professional motto the sentiment expressed by the 19th-century French chemist and statesman Jean-Baptiste Dumas, who once wrote that “the greatest joy of my life has been to accomplish original scientific work, and next to that, to lecture to a set of intelligent students.“ I feel fortunate to be able to do the same here at Macalester College.

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RECENT RESEARCH PROJECTS

Our most recent molecule of interest is gold sulfide, AuS. The gold–sulfur bond is of fundamental interest in the nanoelectronics and molecular self-assembly communities. We are analyzing transitions from the ²Π ground state to three excited doublet states and a low-lying quartet state, all at hyperfine resolution. This work has been carried out by several students, including most recently Sam Gleason and Austin Parsons. We are also collaborating with Tim Steimle's group at ASU on this work.  

We have recently developed new laboratory exercises for the undergraduate physical chemistry lab, now published as three different articles in the Journal of Chemical Education. These experiments involve powder x-ray diffractometry, acoustic interferometry with an Apple iPad, and gas compressibilities. Student collaborators include Andrew Bendelsmith, Kacper Skakuj, Brad Pearlman, Ian Wyse, Sam Gleason and Dalir Kellett, as well as my colleagues Keith Kuwata and Ken Moffett.

Tantalum oxide has been a favorite molecule of ours. We have published two studies of the molecule, with a particular focus on the hyperfine structure of the ground and several excited states. We have one more band in the visible region that we are still working on. Macalester students Kara Manke, Tyson Vervoort, Casey Christopher, Stephanie Lee, Francis Gwandu, Andrew Matsumoto, Ben Knurr, Tom Mahle and Zachary Morrow have all worked on this interesting molecule. 

 

Our interest in gold chemistry and spectroscopy first began by recording unbelievably strong spectra of gold fluoride in the visible region, made from the reaction of sputtered gold with sulfur hexafluoride. We resolved and analyzed hyperfine splittings from both the Au and F nuclei. This work was carried out by Ben Knurr, Elissa Butler, Kara Manke and Tyson Vervoort.

Macalester student Andrew Bendelsmith and I analyzed two electronic bands of tantalum sulfide (TaS) at high resolution in order to understand the hyperfine structure of the molecule. As you can see in these sub-Doppler spectra, the spin of the Ta nucleus is 7/2. My colleague and collaborator Keith Kuwata used density functional theory to obtain calculated values of the magnetic hyperfine parameters that are in excellent agreement with our experimental results. We published our results in the Journal of Molecular Spectroscopy.

Tantalum hydride (TaH) is proving to be a challenging molecule. We have observed several different electronic states in the DCM dye region alone. So far we have published one preliminary paper (with students Casey Christopher and Stephanie Lee) and are now working hard on characterizing all the observed states, work that will occupy some of our time this summer and coming academic year. Sam Gleason, Dalir Kellett and Paul Reischmann are working on this molecule.

FUNDING

The Varberg research group is grateful to the following funding agencies for support of the work in our lab.

2016–2019

$ 223,682

National Science Foundation
RUI Grant

2013–2016

$ 213,447

National Science Foundation
RUI Grant

2009–2013

$ 230,560

National Science Foundation
RUI Grant

2007–2008

$ 50,000

ACS Petroleum Research Fund
UFS Grant

 
 
 
 

2005–2009

$ 228,406

National Science Foundation
RUI Grant

2005–2006

$ 147,537

National Science Foundation
MRI Grant (with co-PIs)

2002–2005

$ 211,209

National Science Foundation
MRI Grant

1998–2003

$ 60,000

Dreyfus Foundation
Henry Dreyfus Teacher–Scholar Award

 
 
 
 

1996–1998

$ 11,269

National Science Foundation
ILI Grant (with co-PIs)

1995–1999

$ 20,000

ACS Petroleum Research Fund
Type G Grant

1994–1996

$ 32,000

Research Corporation
Cottrell College Science Award

1992–1993

$ 41,000

National Science Foundation
NATO Postdoctoral Fellowship

 NSF Logo
 ACS Petroleum Research Fund logo
 Dreyfus Foundation logo
 Research Corporation logo

PUBLICATIONS

*undergraduate collaborator

curriculum vitae

 

2018

36.   A. J. Parsons*, S. P. Gleason* and T. D. Varberg, “High resolution spectroscopy of the a⁴Σ⁻₃⸝₂–X₁²Π₃⸝₂ system of gold monosulphide in the near infrared,” Molecular Physics2018, (published online 08 April 2018).
Article


2017

35.   T. D. Varberg, B. W. Pearlman*, I. A. Wyse*, S. P. Gleason*, D. H. P. Kellett* and K. L. Moffett, “Determining the speed of sound and heat capacity ratios of gases by acoustic interferometry,” Journal of Chemical Education201794, 1995–1998.
Article


2015

34.   D. L. Kokkin, R. Zhang, T. C. Steimle, I. A. Wyse*, B. W. Pearlman* and T. D. Varberg, “Au–S bonding revealed from the characterization of diatomic gold sulfide, AuS,” Journal of Physical Chemistry A2015119, 11659–11667.
Article  |  Supplementary Data

33.   T. D. Varberg and K. Skakuj*, “X-ray diffraction of intermetallic compounds: A physical chemistry labor­atory experiment,” Journal of Chemical Education201592, 1095–1097.
Article  |  Supplementary Data


2014

32.   C. R. Christopher*, S. Y. Lee*, F. B. Gwandu*, A. J. Matsumoto*, B. J. Knurr*, T. K. Mahle*, Z. W. Morrow* and T. D. Varberg, “Rotational and hyperfine analysis of the E²Π₁⸝₂–X²Δ₃⸝₂ electronic transition of TaO,“ Journal of Molecular Spectroscopy2014301, 25–27.
Article  |  Supplementary Data

31.   S. Y. Lee*, C. R. Christopher*, K. J. Manke*, T. R. Vervoort* and T. D. Varberg, “The electronic spec­trum of tantalum hydride and deuteride,” Molecular Physics2014,112, 2424–2432.
Article


2013

30.   T. C. Steimle, R. Zhang, C. Qin and T. D. Varberg, “Molecular-beam optical Stark and Zeeman study of the [17.8]0⁺–X¹Σ⁺ band system of AuF,“ Journal of Physical Chemistry A, 2013, 117, 11737–11744.
Article


2012

29.   A. J. Bendelsmith*, K. T. Kuwata and T. D. Varberg, “Hyperfine structure in the electronic spectrum of TaS,” Journal of Molecular Spectroscopy2012276–277, 14–18.
Article  |  Supplementary Data


2011

28.   T. D. Varberg, A. J. Bendelsmith* and K. T. Kuwata, “Measurement of the compressibility factor of gases: A physical chemistry laboratory experiment,” Journal of Chemical Education201188, 1166–1169.
Article


2010

27.   E. K. Butler*, B. J. Knurr*, K. J. Manke*, T. R. Vervoort* and T. D. Varberg, “Excited electronic states of AuF,” Journal of Physical Chemistry A2010114, 4831–4834.
Article  |  Supplementary Data


2009

26.   B. J. Knurr*, E. K. Butler* and T. D. Varberg, “Electronic spectrum of AuF: Hyperfine structure of the [17.7]1 state,” Journal of Physical Chemistry A2009113, 13428–13435.
Article


2008

25.    D. L. Kokkin, T. P. Troy, M. Nakajima, K. Nauta, T. D. Varberg, G. F. Metha, N. T. Lucas and T. W. Schmidt, “The optical spectrum of a large isolated polycyclic aromatic hydrocarbon: hexa-peri-hexabenzocoronene, C₄₂H₁₈,” Astrophysical Journal, 2008, 681, L49–L51.
Article

24.   K. J. Manke*, T. R. Vervoort*, K. T. Kuwata and T. D. Varberg, “Electronic spectrum of TaO and its hyperfine structure,” Journal of Chemical Physics2008128, 104302/1–6.
Article  |  Supplementary Data


2007

23.   M. A. Roberts*, C. G. Alfonzo*, K. J. Manke*, W. M. Ames*, D. B. Ron* and T. D. Varberg, “Hyperfine structure in the electronic spectrum of ReO,” Molecular Physics2007105, 917–921.
Article  |  Supplementary Data


2006

22.   P. J. Hodges, J. M. Brown and T. D. Varberg, “The ultraviolet spectrum of the CoCl₂ radical, studied at vibrational and rotational resolution,” Journal of Chemical Physics2006124, 204302/1–10.
Article

21.   A. Shayesteh, R. J. Le Roy, T. D. Varberg and P. F. Bernath, “Multi-isotopologue analyses of new vibration–rotation and pure rotation spectra of ZnH and CdH,” Journal of Molecular Spectroscopy2006237, 87–96.
Article  |  Supplementary Data


2004

20.   T. D. Varberg and J. C. Roberts*, “The isotopic dependence of the spin–rotation interaction: The rotational spectrum of cadmium hydride in its X²Σ⁺ state,” Journal of Molecular Spectroscopy2004223, 1–8.
Article


2002

19.   C. T. Kingston, A. J. Merer and T. D. Varberg, “The electronic spectrum of NiCN in the visible region,” Journal of Molecular Spectroscopy2002215, 106–127.
Article


1999

18.   T. D. Varberg, F. Stroh and K. M. Evenson, “Far-infrared rotational and fine-structure transition frequencies and molecular constants of NO in the X²Π (v = 0) state,” Journal of Molecular Spectroscopy1999196, 5–13. 
Article  |  Supplementary Data


1998

17.   T. D. Varberg, J. C. Roberts*, K. A. Tuominen* and K. M. Evenson, “The far-infrared spectrum of deu­terium iodide,” Journal of Molecular Spectroscopy1998191, 384–386.  
Article


1997

16.   F. A. Tezcan*, T. D. Varberg, F. Stroh and K. M. Evenson, “Far-infrared rotational spectra of ZnH and ZnD in the X²Σ⁺ (v = 0) state,” Journal of Molecular Spectroscopy1997185, 290–295. 
Article

15.   N. M. Lakin, T. D. Varberg and J. M. Brown, “The detection of lines in the microwave spectrum of indium hydroxide, InOH, and its isotopomers,” Journal of Molecular Spectroscopy1997183, 34–41. 
Article


1995

14.   M. Bellini, P. De Natale, M. Inguscio, T. D. Varberg and J. M. Brown, “Precise experimental test of models for the breakdown of the Born–Oppenheimer separation: The rotational spectra of isotopic variants of lithium hydride,” Physical Review A,199552, 1954–1960.
Article


1994

13.   R. J. Low, C. J. Whitham, T. D. Varberg and B. J. Howard, “The microwave spectrum of the open-shell complex Ar⋅NO₂,” Chemical Physics Letters1994222, 443–449.  
Article

12.   J. M. Brown, T. D. Varberg, K. M. Evenson and A. L. Cooksy, “The fine-structure intervals of N⁺ by far-infrared laser magnetic resonance,” Astrophysical Journal1994428, L37–L40.  
Article

11.   T. D. Varberg, K. M. Evenson and J. M. Brown, “Detection of OH⁺ in its a¹Δ state by far-infrared laser magnetic resonance,” Journal of Chemical Physics1994,100, 2487–2491. 
Article

10.   T. D. Varberg and K. M. Evenson, “The pure rotational spectra of CuH and CuD in their ground states measured by tunable far-infrared spectroscopy,” Journal of Molecular Spectroscopy1994164, 531–535.  
Article


1993

9.   K. V. Chance, T. D. Varberg, K. Park and L. R. Zink, “The far-infrared spectrum of HI,” Journal of Molecular Spectroscopy1993162, 120–126.  
Article

8.   R. J. Low, T. D. Varberg, J. P. Connelly, A. R. Auty, B. J. Howard and J. M. Brown, “The hyperfine structures of CuCl and CuBr in their ground states studied by microwave Fourier transform spectroscopy,” Journal of Molecular Spectroscopy1993161, 499–510.  
Article

7.   T. D. Varberg and K. M. Evenson, “Laser spectroscopy of carbon monoxide: A frequency reference for the far-infrared,” IEEE Transactions on Instrumentation and Measurement199342, 412–414.  
Article

6.   T. D. Varberg and K. M. Evenson, “The rotational spectrum of OH in the v = 0–3 levels of its ground state,” Journal of Molecular Spectroscopy1993157, 55–67.  
Article


1992

5.   T. D. Varberg, J. A. Gray, R. W. Field and A. J. Merer, “Reanalysis and extension of the MnH A⁷Π–X⁷Σ⁺(0,0) band: Fine structure and hyperfine-induced rotational branches,” Journal of Molecular Spectroscopy1992156, 296–318.  
Article

4.   T. D. Varberg and K. M. Evenson, “Accurate far-infrared rotational frequencies of carbon monoxide,” Astrophysical Journal1992385, 763–765. 
Article


1991

3.   T. D. Varberg, R. W. Field and A. J. Merer, “Elucidation of electronic structure by the analysis of hyper­fine interactions: The MnH A⁷Π–X⁷Σ⁺(0,0) band,” Journal of Chemical Physics199195, 1563–1576. 
Article


1990

2.   T. D. Varberg, R. W. Field and A. J. Merer, “Hyperfine structure of the MnH X⁷Σ⁺state: A large gas-to-matrix shift in the Fermi contact interaction,” Journal of Chemical Physics199092, 7123–7127. 
Article


1989

1.   T. D. Varberg, E. J. Hill and R. W. Field, “Laser spectroscopy of CoH: Spin–orbit splitting of the ground state,” Journal of Molecular Spectroscopy1989138, 630–637.  
Article